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How does the reaction for propane/oxygen proceed?

I have been reading this and the reaction is
$$\ce{C3H8 + O2 -> 2 CO2 + 4 H2O}$$

I am looking for two things:

A route of attack: first proton attacks the carbonyl group in the first step
An intermediate: Shouldn’t there be some intermediate in the reaction?

A:

You could also opt for a collision and proton transfer.
The lone pair of oxygen is far too unstable to be stable in the carbonyl centre of propane. I think the intermediate of your question is aldehyde.

A:

You are right that the alkyl radicals will be very unstable because the alkene is a better leaving group. One of the most common ways to leave groups is to do an elimination reaction. Reactions with peroxy compounds tend to be very quick so this kind of process is the most reasonable.
When a peroxy compound reacts with an alkene the peroxy group is cleaved, forming alkyl peroxide and propene. The peroxide is quite stable and the alkyl radical is nucleophilic to the peroxide, forming a peroxyalkyl radical and the original alkene. This is not a radical addition. The radical reacts chemically and the carbon is removed from the alkene.

A:

This is a peroxide coupling reaction. This is in the same family as the Grignard reaction.
The reactions are similar. We have two highly reactive chemicals react in a radical. They then react and form a radical. The addition of the alkyl radical to the peroxide displaces the peroxide and removes carbon.

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I’m so proud of our great neighbours to the north. With such a history of fighting dictatorship, only Canadians could have forged such a remarkable system of law and democracy.

I’m also very fond of Americans. You seem to have the right values. But at times you seem to have not understood how other cultures operate. The overly polite Canadian may be one of my favourite Canadian traits.

The U.S. has what is best described as a democratic republic and a constitutional system; both of which allow for regular elections and provide citizens with an opportunity to change their government. In the U.S. citizens have an expectation of the system and their government upholding the law. It provides an opportunity for people to demand what they want.

To me the right of a country to be governed by their own laws is a fundamental one. Neither Canada nor the U.S. can claim the right to govern a country with the right to end the lives of their own citizens.

There is no such law in the U.S. nor there is a president seeking a law to create one, and Canada is not creating a law to take away another country’s right to end the lives of citizens.

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